Dibenzo[b,f]phosphepines: Novel Phosphane–Olefin Ligands for Transition Metals
نویسندگان
چکیده
منابع مشابه
Transition metals catalyzed synthesis novel heterocyclic compounds
Based on my research experience and academic career, my research plan is to develop new synthetic reactions to create heterocyclic molecules having useful properties as functional materials or biological activities. Reactions I am going to study on can be classified into the following two categories. Project 1: Transition metal-catalyzed cascade cyclization and oxidative cross couplings reactio...
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Deltahedral Zintl ions Ge9 are disubstituted with organic fragments that have various functional groups. Some of the latter are appropriate for coordination to transition-metals to eventually form coordination compounds where the organo-Zintl species act as ligands. Examples of [Ge9R2] include R 1⁄4 eCH]CHIm(Me), eCH]CHeC6H4eOMe, eCH]CH-Fc, eCH]CHe(CH2)4eC^CH, eCH]CHeC6H4eC^CH, CH] CHeC6H4eNH2,...
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The [3 + 2] cycloaddition of azides and acetylenes followed by nitrogen quaternization was applied for the generation of novel and highly modular triazolium salts. The selective substitution of the 1,3,4-substitution pattern presets such salts as precursors for a new class of abnormal carbene ligands, thus expanding the family of these high-impact ligands. Metalation of the triazolium salts is ...
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ژورنال
عنوان ژورنال: Organometallics
سال: 2012
ISSN: 0276-7333,1520-6041
DOI: 10.1021/om301012z